Visible‐Light‐Mediated Aromatic Substitution Reactions of Cyanoarenes with 4‐Alkyl‐1,4‐dihydropyridines through Double Carbon–Carbon Bond Cleavage
نویسندگان
چکیده
منابع مشابه
Quantum Chemical Studies of Aromatic Substitution Reactions
In this thesis, density functional theory (DFT) is used to investigate the mechanisms and reactivities of electrophilic and nucleophilic aromatic substitution reactions (SEAr and SNAr respectively). For SEAr, the σ-complex intermediate is preceded by one (halogenation) or two (nitration) π-complex intermediates. Whereas the rate-determining transition state (TS) for nitration resembles the seco...
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ژورنال
عنوان ژورنال: ChemCatChem
سال: 2016
ISSN: 1867-3880,1867-3899
DOI: 10.1002/cctc.201600037